Adams negotiated the "Transcontinental Treaty" with Spain in 1819 that turned Florida over to the U.S. and resolved border issues regarding the Louisiana Purchase. The treaty recognized Spanish control of Texas (a claim taken up by Mexico when it declared independence of Spain). The post of Secretary of State was the normal path to the White House. After 1820 Adams, intent on winning the presidency, was less successful at the State Department. He failed to make key commercial treaties because he feared the necessary American concessions would be used to attack his candidacy. Instead the nation suffered from trade wars that could have been prevented.

1824–25 presidential election
As the election of 1824 drew near people began looking for candidates. New England voters admired Adams' patriotism and political skills and it was mainly due to their support that he entered the race. The old caucus system of the Democratic-Republican Party had collapsed; indeed the entire First Party System had collapsed and the election was a free-for-all based on regional support. Adams had a strong base in New England. His opponents included John C. Calhoun, William Crawford, Henry Clay and the hero of New Orleans, Andrew Jackson. During the campaign Calhoun dropped out, and Crawford fell ill giving further support to the other candidates. When the election day came, Andrew Jackson won, although narrowly, pluralities of the popular and electoral votes, but not the necessary majority of electoral votes.

Under the terms of the Twelfth Amendment, the presidential election was thrown to the House of Representatives to vote on the top three candidates: Jackson, Adams, and Crawford. Clay had come in fourth place and thus was ineligible, but he retained considerable power and influence as Speaker of the House. Crawford was unviable due to the stroke.

Clay's personal dislike for Jackson and the similarity of his American System to Adams' position on tariffs and internal improvements caused him to throw his support to Adams, who was elected by the House on February 9, 1825, on the first ballot. Adams' victory shocked Jackson, who had gained the plurality of the electoral and popular votes and fully expected to be elected president. When Adams appointed Clay as Secretary of State—the position that Adams and his three predecessors had held before becoming President—Jacksonian Democrats were outraged, and claimed that Adams and Clay had struck a "corrupt bargain." This contention overshadowed Adams' term and greatly contributed to Adams' loss to Jackson four years later, in the 1828 election.

Presidency 1825–1829
Adams served as the sixth President of the United States from March 4, 1825, to March 4, 1829. He took the oath of office on a book of laws, instead of the more traditional Bible, to preserve the separation of church and state.

Politics
Adams' singular intelligence, vast experience, unquestionable integrity, and devotion to his country should have made him a great chief executive. But, like his father, he lacked political sense and an ability to command public support, and his contentious spirit spelled defeat for him personally and for many of his policies. He proposed a comprehensive program of internal improvements (roads, ports and canals), the creation of a national university, and federal support for the arts and sciences. He favored a high tariff to encourage the building of factories, and restricted land sales to slow the movement west. Opposition from the states' rights faction quickly killed the proposals,[18] Even more serious was the attack by the followers of Jackson, who accused him of being a partner to a "corrupt bargain" to obtain Clay's support in the election and then appoint him secretary of state. Refusing to play politics, Adams did little or nothing to build up a personal following committed to his re-election. He refused to discharge federal officeholders when they actively joined the opposition, and even considered appointing Jackson to his cabinet. Losing control of Congress in the elections of 1826, he still persisted in his independent policies and thus insured his own overwhelming defeat by Jackson two years later. He was particularly embittered by the unfounded accusations of fraud and extravagance made against him during the campaign by his opponents (not to mention the false accusation that he had pimped for the Czar of Russia). The Adams administration recorded no major legislative, diplomatic, military or administrative achievements. Congress did pass the high Tariff of 1828—the "tariff of abominations" that created a violent outcry especially in South Carolina. Jackson defeated Adams in a landslide in 1828, and created the modern Democratic party thus inaugurating the Second Party System.

Domestic policies
During his term, Adams worked on developing the American System, consisting of a high tariff to support internal improvements such as road-building, and a national bank to encourage productive enterprise and form a national currency. In his first annual message to Congress, Adams presented an ambitious program for modernization that included roads, canals, a national university, an astronomical observatory, and other initiatives. The support for his proposals was limited, even from his own party. His critics accused him of unseemly arrogance because of his narrow victory. Most of his initiatives were opposed in Congress by Jackson's supporters, who remained outraged over the 1824 election.

Nonetheless, some of his proposals were adopted, specifically the extension of the Cumberland Road into Ohio with surveys for its continuation west to St. Louis; the beginning of the Chesapeake and Ohio Canal, the construction of the Delaware and Chesapeake Canal and the Portland to Louisville Canal around the falls of the Ohio; the connection of the Great Lakes to the Ohio River system in Ohio and Indiana; and the enlargement and rebuilding of the Dismal Swamp Canal in North Carolina.

One of the issues which divided the administration was protective tariffs. Henry Clay was a leading advocate, but Vice President John C. Calhoun was an opponent. After Adams lost control of Congress in 1827, the situation became more complicated. By signing into law the Tariff of 1828 (also known as the Tariff of Abominations), extremely unpopular in the South, he limited his chances to achieve more during his presidency.

Adams and Clay set up a new party, the National Republican Party, but it never took root in the states. In the elections of 1826, Adams and his supporters lost control of Congress. New York Senator Martin Van Buren, a future president and follower of Jackson, became one of the leaders of the Senate.

Much of Adams' political difficulties were due to his refusal, on principle, to replace members of his administration who supported Jackson (contending that no one should be removed from office except for incompetence). For example, his Postmaster General, John McLean, continued in office through the Adams administration, although he was using his powers of patronage to curry favor with Jacksonites.

Another blow to Adams' presidency was his generous policy toward Native Americans. Settlers on the frontier, who were constantly seeking to move westward, cried for a more expansionist policy. When the federal government tried to assert authority on behalf of the Cherokees, the governor of Georgia took up arms. In contrast, Andrew Jackson and Martin Van Buren instigated the policy of Indian removal to the west (i.e. the Trail of Tears). Adams defended his domestic agenda as continuing Monroe's policies.

Foreign policies
Adams is regarded as one of the greatest diplomats in American history, and during his tenure as Secretary of State he was the chief designer of the Monroe Doctrine.

On July 4, 1821, he gave an address to Congress:

... But she goes not abroad, in search of monsters to destroy. She is the well-wisher to the freedom and independence of all. She is the champion and vindicator only of her own.

During his term as president, however, Adams achieved little of consequence in foreign affairs. A reason for this was the opposition he faced in Congress, where his rivals prevented him from succeeding.

Among the few diplomatic achievements of his administration were treaties of reciprocity with a number of nations, including Denmark, Mexico, the Hanseatic League, the Scandinavian countries, Prussia and Austria. However, thanks to the successes of Adams' diplomacy during his previous eight years as Secretary of State, most of the foreign policy issues he would have faced had been resolved by the time he became President.

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